What are the chances I'll get a job at a hotel/motel, with no experience?

Working the front desk.

Have you ever worked at a hotel?

Did you like it?

If you have skills they can use, it is possible. For example, working on the front desk requires good communication and computer skills. If you are able to show those, then you might have a chance, especially at the smaller hotels. Forget about being employed at the big hotel chains, at elast for now. Good luck!